ASTM D4735-24 - Standard Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography
Standard Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography
| Standard number: | ASTM D4735-24 |
| Released: | 01.11.2024 |
| Status: | Active |
| Pages: | 7 |
| Section: | 06.04 |
| Keywords: | Supporting data have been filed at ASTM International Headquarters and may be obtained by requesting Research Report . Contact ASTM Customer Service at www.astm.org/contact. ; benzene; capillary column; flame photometric detector; gas chromatography; pulsed flame photometric detector; split/splitless injector; thiophene; |
1.1 This test method covers the determination of thiophene in refined benzene.
1.2 This test method is applicable to samples with thiophene concentrations in the range from 0.80 mg/kg to 1.80 mg/kg for the Flame Photometric Detector (FPD), and from 0.14 mg/kg to 2.61 mg/kg for the Pulsed Flame Photometric Detector (PFPD). For the PFPD, the minimum level of quantitation (LOQ) is 0.14 mg/kg and the minimum level of detection (LOD) is 0.04 mg/kg. With careful analytical technique, and/or replicates, this method can be used to successfully analyze concentrations below the current LOD. The range of the test method may be extended by modifying the sample injection volume, split ratios, calibration range, or sample dilution with thiophene-free solvent.
Note 1: See Appendix X1 for additional information on calculation of LOD.
Note 2: LOD and LOQ were calculated using data from ASTM Research Report RR:D16-1038.2
1.3 This test method has been found applicable to benzene characteristic of the type described in Specifications D2359 and D4734 and may be applicable to other types or grades of benzene only after the user has demonstrated that the procedure can completely resolve thiophene from the other organic contaminants contained in the sample.
1.4 The following applies for the purposes of determining the conformance to applicable specifications using this test method, results shall be rounded off in accordance the rounding-off method of Practice E29.
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.