ASTM D5739-06R20 - Standard Practice for Oil Spill Source Identification by Gas Chromatography and Positive Ion Electron Impact Low Resolution Mass Spectrometry

1.1 This practice covers the use of gas chromatography and mass spectrometry to analyze and compare petroleum oil spills and suspected sources.

1.2 The probable source for a spill can be ascertained by the examination of certain unique compound classes that also demonstrate the most weathering stability. To a greater or lesser degree, certain chemical classes can be anticipated to chemically alter in proportion to the weathering exposure time and severity, and subsequent analytical changes can be predicted. This practice recommends various classes to be analyzed and also provides a guide to expected weathering-induced analytical changes.

1.3 This practice is applicable for moderately to severely degraded petroleum oils in the distillate range from diesel through Bunker C; it is also applicable for all crude oils with comparable distillation ranges. This practice may have limited applicability for some kerosenes, but it is not useful for gasolines.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.