BS EN 16691:2015
Water quality. Determination of selected polycyclic aromatic hydrocarbons (PAH) in whole water samples. Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography mass spectrometry (GC-MS)
Standard number: | BS EN 16691:2015 |
Pages: | 36 |
Released: | 2015-09-30 |
ISBN: | 978 0 580 84469 0 |
Status: | Standard |
BS EN 16691:2015
This standard BS EN 16691:2015 Water quality. Determination of selected polycyclic aromatic hydrocarbons (PAH) in whole water samples. Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography mass spectrometry (GC-MS) is classified in these ICS categories:
- 13.060.50 Examination of water for chemical substances
This European Standard specifies a method for the determination of 7 polycyclic aromatic hydrocarbons (PAH) in whole water samples listed in Table 1. The method uses solid-phase disk extraction with SPE-disks followed by gas chromatography-mass spectrometry (GC-MS). It is applicable to the analysis of PAHs in surface water containing suspended particulate matter (SPM) up to 500 mg/l (whole water samples), drinking water and groundwater.
The lower and upper limit of the working range depends on the matrix, on the specific compound to be analyzed and on the sensitivity of the mass spectrometric detection unit. The limit of quantification (LOQ) determined in the validation is given in Table 1. The upper limit of the working range is approximately 2 000 ng/l.
This method is, with some modifications suitable for the analysis of waste water. This method is applicable to other PAH 1) , provided the method is validated for each PAH.
Substance | Molecular formula | Molar mass | EC number a | CAS-RN b | LOQ c |
---|---|---|---|---|---|
g/mol | ng/l | ||||
anthracene | C14H10 | 178,23 | 204–371–1 | 120–12–7 | 0,24 |
fluoranthene | C16H10 | 202,26 | 205–912–4 | 206–44–0 | 2,1 |
benzo[b]fluoranthene | C20H12 | 252,32 | 205–911–9 | 205–99–2 | 0,56 |
benzo[k]fluoranthene | C20H12 | 252,32 | 205–916–6 | 207–08–9 | 0,44 |
benzo[a]pyrene | C20H12 | 252,32 | 200–028–5 | 50–32–8 | 0,33 |
benzo[ghi]perylene | C22H12 | 276,34 | 205–883–8 | 191–24–2 | 0,44 |
indeno[1,2,3-cd]pyrene | C22H12 | 276,34 | 205–893–2 | 193–39–5 | 0,42 |
EC Number: European inventory of existing commercial substances (EINECS) or European list of notified chemical substances (ELINCS).
CAS-RN: Chemical Abstracts Service Registry Number.
For the determination of the LOQ the procedure given in NEN 7777+C1:2012 [12] was used.