An electrochemical reference system for use in different solvent media. The decamethylated ferricinium/ferrocene redox couple
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Standard number:
PD IEC/TR 62456:2007
Pages:
10
Released:
2007-03-29
ISBN:
978 0 580 50855 4
Status:
Standard
DESCRIPTION
PD IEC/TR 62456:2007
This standard PD IEC/TR 62456:2007 An electrochemical reference system for use in different solvent media. The decamethylated ferricinium/ferrocene redox couple is classified in these ICS categories:
71.040.40 Chemical analysis
17.020 Metrology and measurement in general
71.040.30 Chemical reagents
to present the background considerations which led to this compilation of potentials of the aqueous saturated calomel electrode compared to the cyclovoltametric data for a glassy carbon electrode in various solvent media. A tabulation of working potentials of this electrode pair in various solvent media is presented. A comparison of the cyclovoltametric scans for the ferricinium/ferrocene and deamethyl derivatized ferricinium/ferrocene redox couple system is presented and important features are discussed